Measuring the charging states of atmospheric particles offers accurate data for formulating advanced models on the effects of particulates for human health
Published online 27 March 2019
The Keio Measurement system of Aerosol Charging State (K-MACS) ©RTCorp
Inhalation of particulate matter is one of the top ten risks to human health according to the World Health Organization (WHO). In 2016, as many as 4.2 million people died due to the effects of particulates in the air. With these alarming statistics, it is not surprising that there have been increased calls for greater awareness and monitoring of the air for potentially deadly particulates.
"The health risks of inhaling particles less than 2.5 micrometers, so-called PM2.5, are well documented with environmental agencies monitoring particle-concentrations and issuing warnings to the public about dangerous levels of PM2.5 in the air," says environmental scientist Tomoaki Okuda, an associate professor at the Department of Applied Chemistry, Keio University. "However, recent reports indicate that singly charged particles are about six times more likely to be adsorbed into the respiratory tract than uncharged particles. So, an accurate assessment of the effect of air-borne particles on human health requires a much deeper understanding of not only the size of particles, but also their physico-chemical properties including charge and surface structure. My research is focused on determining the charging state of particles in the air, which, surprisingly, is not well understood."
Keio Measurement system of Aerosol Charging State (K-MACS)
Okuda and colleagues developed K-MACS (Fig. 1)1, 2 as an inexpensive and versatile system to continuously separate and quantify the charging state of atmospheric particles ranging in size from 300 nm to 500 nm for short durations over a period of 12 months. "We studied this range of particles because they have a larger concentration in the air," says Okuda. Measurements of these particles were taken at Keio University's Yagami Campus from April 2017 to February 2018.
Illustration and photograph of the Keio Measurement system of Aerosol Charging State (K-MACS) ©Keio University
The two main findings were that the charging state of the atmospheric particles was different from the results of theoretical studies to-date (Fig. 2), and that the particle charging state fluctuated markedly with changing atmospheric conditions (water vapor amount and entrained air mass) due to seasonal variations.3
"These results offer new insights into the changes of the charging state of particles," says Okuda. "They will play an important role in the accurate evaluation of the effects of atmospheric particles on human health on a global scale."
(Left) Charge distributions of measured (green) and theoretically calculated particles.
(Right) Variation of the volumetric humidity versus charged particles fraction.
Related research conducted by Tomoaki Okuda
Okuda conducted a theoretical assessment of the performance of a parallel plate particle separator (K-MACS) instrument designed to measure the charging state of PM2.5 particles. Results yielded an optimal voltage to maximize the types of particles.2 This research addresses the question of what happens to aerosol particles in humid conditions, such as haze. A discrete element model showed a correlation between relative humidity and the amount of water contained in the particles that were found to be charged negatively or positively.4
About the researcher
Tomoaki Okuda― Associate ProfessorDepartment of Applied Chemistry, Faculty of Science and Technology
Tomoaki Okuda has participated in many international joint research projects relating to air pollution around East Asia. His current research focuses on the physical and chemical properties of aerosols which provide metrics for their adverse health effects. He is a recipient of several awards, including the 2015 Asian Young Aerosol Scientist Award.
- Tomoaki Okuda, Yuma Gunji & I.W. Lenggoro, Measurement of the electrostatic charging state of individual particles in ambient aerosol using Kelvin Probe Force Microscopy, Earozoru Kenkyu 30, 190-197 (2015) | article (Japanese language only)
- Takuto Yonemichi, Koji Fukagata, Kentaro Fujioka & Tomoaki Okuda, Numerical simulation of parallel-plate particle separator for estimation of charge distribution of PM2.5, Aerosol Science and Technology (2019) | article
- Ayumi Iwata, et al., Seasonal variation in atmospheric particle electrostatic charging states determined using a parallel electrode plate device, Atmospheric Environment, 203, 62-69 (2019) | article
- Yuanping He et al., Atmospheric humidity and particle charging state on agglomeration of aerosol particles, Atmospheric Environment, 197, 141-149 (2019) | article